Thermodynamics of Melts
Thermodynamic properties of one-component and multicomponent systems, equilibrium in a homogeneous multicomponent system and equilibrium conditions in a heterogeneous system, the Gibbs’ phase rule and its application in status diagrams, are considered. Nonideally diluted and regular solutions are analyzed; basic thermodynamic functions are obtained for binary regular solutions. The main provisions of quasi-chemical theory of solutions and its application in regular solutions are given. Quasi-chemical interpretation of short-range order is seen. Component solubility in different phases is studied. Based on status diagrams, vibrational entropy of dissolved impurity was estimated. The…
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